Structural Diversity in Hybrid Binary Superlattices Coassembled From Colloidal Nanocrystals and Submicrometer Colloids

colloids produces non-close-packed NC superlattices that are challenging to achieve through direct assembly. By addressing colloidal incompatibility through ligand design, this work paves the way for bridging nanoscale and submicroscale building blocks, facilitating the design of hybrid superlattices with wide applications in photonics, sensing, catalysis, and multifunctional metamaterials.