材料科学
阳极
异质结
硒化物
电化学
退火(玻璃)
化学工程
过渡金属
储能
金属
电极
复合材料
光电子学
冶金
催化作用
物理化学
化学
硒
热力学
物理
生物化学
功率(物理)
工程类
作者
Shengkai Li,Haiyan Zhang,Shangshang Zhang,Zhenjiang Liu,Changsheng Yang,Yong Xu
标识
DOI:10.1016/j.mtener.2023.101309
摘要
Transition metal selenides can be potentially implemented as a new generation of sodium storage anode owing to their abundance and high theoretical specific capacity. However, their practical applications are limited by large volume changes and slow kinetics. Therefore, the construction of transition metal selenide heterojunctions with long cycle stability and high capacity as anodes in sodium ion batteries remains challenging. In this study, carbon coated CuFeSe2/Cu2Se heterojunctions (CFS/CS@C) were successfully prepared via a simple aging and annealing strategy. The abundant heterojunction interfaces and carbon layers accelerated charge transfer, promoted the reaction kinetics, enhanced the electrical conductivity, and extended the cycle life. Consequently, the target material yielded ultra-long cycle stability (301.2 mAh/g at 10.0 A/g after 3000 cycles) and excellent rate performance (330.96 mAh/g at 20 A/g). The directly constructed full cell also exhibited remarkable cycling stability (138.6 mAh/g after 200 cycles at 0.5 A/g). Accordingly, this work demonstrated the construction of transition metal selenide composites as high-performance electrochemical energy storage electrodes.
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