催化作用
煅烧
材料科学
化学工程
多孔性
催化燃烧
甲苯
无定形固体
介孔材料
热稳定性
催化剂载体
复合材料
化学
有机化学
工程类
作者
Yuntai Xi,Fang Dong,Zhongying Ji,Zhicheng Tang,Jiyi Zhang
标识
DOI:10.1016/j.jclepro.2022.134694
摘要
The shortcomings of Co-based powder catalysts such as amorphous susceptibility to loss and high influence by pressure drop have become the key factors affecting their catalytic activity. In this paper, two methods were proposed to prepare novel monolithic Co3O4/SiO2 catalysts by 3D direct ink writing (DIW) technology: (1) one-step method of printing the active component with supports, (2) two-step method of printing the support first, and then loading the active components. The results showed that the monolithic catalyst prepared by the two-step method possessed more abundant Co3+ and lattice oxygen (Olatt) species than the one-step method, which jointly promoted the catalytic conversion of toluene. However, the catalyst printed by the one-step method had a stronger interaction between the active component and the support, showing better thermal stability and water resistance. In addition, the SiO2 support (the calcined product after SiO2 ink printing) enhances the activity, stability, compression resistance, while the N–SiO2 support (the calcined product after SiO2 precursor ink printing) can effectively prevent blockage of the pore structure by the binder and increase physical properties such as pore volume and specific surface area of Co3O4/SiO2 catalyst.
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