Modeling of Concrete Deterioration under External Sulfate Attack and Drying–Wetting Cycles: A Review

This paper comprehensively summarizes moisture transport, ion transport, and mechanical damage models applied to concrete under sulfate attack and drying–wetting cycles. It highlights the essential aspects and principles of each model, emphasizing their significance in understanding the movement of moisture and ions, as well as the resulting mechanical damage within the concrete during these degradation processes. The paper critically analyzes the assumptions made in each model, shedding light on their limitations and implications for prediction accuracy. Two primary challenges faced by current models under sulfate attack and drying–wetting cycles are identified: the limited consideration of the coupled effects of chemical and physical attacks from sulfate, and the unclear mechanism of the sulfate attacks. Future research directions are proposed, focusing on exploring the transport mechanism of sulfate ions under various driving forces and further clarifying the crystallization process and expansion damage mechanism in concrete pores. Addressing these research directions will advance our understanding of sulfate attack under drying–wetting cycles, leading to improved models and mitigation strategies for enhancing the durability and performance of concrete structures.