Copper-catalyzed asymmetric hydroboration of 1,3-enynes with pinacolborane to access chiral allenylboronates
化学
硼氢化
催化作用
组合化学
铜
有机化学
作者
Hui Leng Sang,Songjie Yu,Shaozhong Ge
出处
期刊:Organic chemistry frontiers [The Royal Society of Chemistry] 日期:2018-01-01卷期号:5 (8): 1284-1287被引量:76
标识
DOI:10.1039/c8qo00167g
摘要
A wide range of functionalized 1,3-enynes undergo hydroboration with pinacolborane to produce enantiomerically enriched allenylboronates in the presence of a chiral copper catalyst.