化学
杂原子
表面改性
碳纤维
组合化学
碳原子
分子
有机化学
戒指(化学)
复合数
物理化学
复合材料
材料科学
作者
Xiaohua Cai,Mengzhi Yang,Bing Xie
出处
期刊:Letters in Organic Chemistry
[Bentham Science]
日期:2019-08-23
卷期号:16 (10): 779-801
被引量:2
标识
DOI:10.2174/1570178616666190123131353
摘要
The selective functionalization of unactivated C(sp3)-H bonds has been regarded as an efficient and atom-economical approach for the formation of carbon-carbon or carbon-heteroatom bonds in modern organic synthesis. Especially, the oxidative activation of C(sp3)–H bonds adjacent to a heteroatom exhibits quite significant features in synthetic chemistry. For example, the direct functionalizations of amines, amides and ethers present important alternative tactics for the synthesis of various novel and useful molecules from simple starting materials. Many remarkable achievements in the area had continuously been made in the past decades. Here we reviewed recent investigations on the transformations of C(sp3)-H bond adjacent to a heteroatom.
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