马尔科夫尼科夫法则
化学
催化作用
选择性
羰基化
钯
有机化学
磷化氢
均相催化
组合化学
区域选择性
一氧化碳
作者
Haoquan Li,Kaiwu Dong,Haijun Jiao,Helfried Neumann,Ralf Jackstell,Matthias Beller
出处
期刊:Nature Chemistry
[Springer Nature]
日期:2016-09-05
卷期号:8 (12): 1159-1166
被引量:121
摘要
The selective formation of Markovnikov products in carbonylation reactions is a challenging problem, especially from unactivated substrates. Now, a highly Markovnikov-selective alkoxycarbonylation reaction is described using a catalyst system based on palladium and the cataCXium ligand POMeCy(Ph). The resulting branched carboxylates are important structural components in many flavour and fragrance products.
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