材料科学
电解质
法拉第效率
介电谱
石墨
化学工程
X射线光电子能谱
快离子导体
分析化学(期刊)
电化学
电极
复合材料
化学
有机化学
物理化学
工程类
作者
Giovanna Maresca,Akiko Tsurumaki,N. Suzuki,Tomoyuki Tsujimura,Yûichi Aihara,Maria Assunta Navarra
标识
DOI:10.1002/celc.202001291
摘要
Abstract A study on the interfacial properties between a solid glassy electrolyte, LiI‐Li 3 PS 4 (LPSI), and graphite (MAG) composite electrodes was carried out with the aim of reducing or even eliminating the irreversible capacity during the 1 st charge‐discharge cycle. The performances of all‐solid‐state MAG|LPSI|Li cells were compared with those of conventional liquid cells. To reinforce a well‐distributed conductive path in MAG as well as at the MAG/LPSI interface, the type of electron conducting additive and the pressure during cell preparation were optimized. Specific functions of the conducting additive were demonstrated, where the sub‐micrometric carbon fibers allowed better galvanostatic performance in the solid‐state configuration by virtue of their high aspect ratio. The coulombic efficiency of solid‐state cells was improved from 46 to 99 % and the reversible capacity value from 100 to 270 mAh g −1 , by increasing the pressure from 2 to 4 ton. The interfacial stability of LPSI was also evaluated by impedance spectroscopy of MAG|MAG and Li|Li cells over time. Although ionic resistance of LPSI was higher than a conventional liquid electrolyte, LPSI exhibited controlled interfacial resistance.
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