化学
偶氮苯
光异构化
金属有机骨架
螺吡喃
二芳基乙烯
光致变色
小提琴手
纳米技术
配体(生物化学)
光化学
分子
异构化
有机化学
催化作用
受体
材料科学
吸附
生物化学
作者
Allison M. Rice,Corey R. Martin,Vladimir A. Galitskiy,Anna A. Berseneva,Gabrielle A. Leith,Natalia B. Shustova
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2019-10-22
卷期号:120 (16): 8790-8813
被引量:279
标识
DOI:10.1021/acs.chemrev.9b00350
摘要
In this Review, we showcase the upsurge in the development and fundamental photophysical studies of more than 100 metal–organic frameworks (MOFs) as versatile stimuli-responsive platforms. The goal is to provide a comprehensive analysis of the field of photoresponsive MOFs while delving into the underlying photophysical properties of various classes of photochromic molecules including diarylethene, azobenzene, and spiropyran as well as naphthalenediimide and viologen derivatives integrated inside a MOF matrix as part of a framework backbone, as a ligand side group, or as a guest. In particular, the geometrical constraints, photoisomerization rates, and electronic structures of photochromic molecules integrated inside a rigid MOF scaffold are discussed. Thus, this Review reflects on the challenges and opportunities of using photoswitchable MOFs in next-generation multifunctional stimuli-responsive materials while highlighting their use in optoelectronics, erasable inks, or as the next generation of sensing devices.
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