化学
硅烷化
分子间力
芳基
硅
组合化学
催化作用
纳米技术
立体化学
分子
有机化学
烷基
材料科学
作者
Jiawei Guo,Shunfa Liu,Jun Jing,Yu Fan,Yingjuan Fu,Shiyang Liu,Wanshu Wang,Gao L,Zhenlei Song
出处
期刊:Organic Letters
[American Chemical Society]
日期:2023-10-04
卷期号:25 (40): 7428-7433
被引量:1
标识
DOI:10.1021/acs.orglett.3c03014
摘要
A B(C6F5)3-catalyzed controllable inter/intra-/intermolecular Si-C bond formation process has been developed from trihydrosilane and dienamide with alkenes, anilines, or aryl iodides. A variety of 1,4-azasilinanes have been generated with diverse exo-cyclic heteroleptic disubstitutions on silicon, thereby expanding the range of silaazacyclic rings available for the discovery of silicon-containing drugs.
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