双金属片
X射线光电子能谱
钛
材料科学
扫描电子显微镜
吸附
金属
反应性(心理学)
粉末衍射
选择性
光谱学
能量色散X射线光谱学
金属有机骨架
分析化学(期刊)
化学工程
核化学
催化作用
结晶学
冶金
物理化学
化学
复合材料
有机化学
医学
替代医学
物理
病理
量子力学
工程类
作者
Suhui Liu,Xiaomin Li,Xiaoqing Wang,Ye Li,Feifei Zhang,Libo Li,Jinping Li,Jiangfeng Yang
摘要
Titanium (Ti)-based metal-organic frameworks (Ti-MOFs) have attracted intensive research attention due to their low toxicity and high abundance of titanium. However, limited by the high reactivity of titanium species in the reaction system, the construction of Ti-MOFs still faces great challenges. Herein, we successfully introduced Ti into MOF-74 using a one-pot method. Powder X-ray diffraction (PXRD) combined with X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma (ICP) spectroscopy confirmed that the Ti(IV) ions were uniformly inserted into the MOF-74 structure. Our scanning electron microscopy (SEM)/energy-dispersive spectrometry (EDS) analysis showed that the Ti content was up to 44% with good sample homogeneity. The adsorption selectivity of Ti0.44/Ni0.56-MOF-74 at 1.0 bar and 298 K for C2H2/C2H4 and C2H2/CO2 (50/50, v/v) mixtures was 4.9 and 6.8, respectively, which are higher than that of pristine Ni-MOF-74. The results of our breakthrough simulation experiments revealed that the adsorption and separation performances of Ti0.44/Ni0.56-MOF-74 were greatly improved. This study provided insights for the construction of Ti-based bimetallic MOFs used for the separation of light hydrocarbons.
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