二次谐波产生
发色团
材料科学
红外线的
双折射
非线性光学
非线性光学
光电子学
激光器
二次谐波成像显微术
光学
非线性系统
光化学
化学
量子力学
物理
作者
Xin Zhao,Chensheng Lin,Chao Wang,Haotian Tian,Peng Dong,Tao Yan,Bingxuan Li,Ning Ye,Min Luo
标识
DOI:10.1016/j.scriptamat.2023.115935
摘要
Infrared (IR) nonlinear optical (NLO) crystals are of great significance in modern laser technology, and metal chalcogenides are receiving increasing interest as promising IR NLO candidates. To explore new IR NLO materials with enhanced properties, two quaternary chalcogenides with multiple chromophores, KCu4AsS4 and RbCu4AsS4, were synthesized using the solvothermal method. KCu4AsS4 and RbCu4AsS4 feature 2D [Cu6As2S6]∞ anionic layers with multiple chromophores, and exhibit strong phase-matched second-harmonic generation (SHG) responses (1.8–2.0 × AgGaS2), wide band gaps, suitable birefringence (0.083 and 0.074 @ 2050 nm) and wide infrared transparency. The theoretical calculation results suggest that the strong SHG responses are ascribed to the 2D [Cu6As2S6]∞ anionic layers.
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