材料科学
咪唑酯
检出限
电化学
纳米复合材料
纳米颗粒
电化学气体传感器
纳米技术
化学工程
核化学
吸附
色谱法
物理化学
电极
有机化学
化学
工程类
作者
Yunhang Liu,Tingting Wu,Hongyuan Zhao,Gan Zhu,Fang Li,Meimei Guo,Qiwen Ran,Sridhar Komarneni
标识
DOI:10.1016/j.ceramint.2023.04.217
摘要
A sensitive carbendazim (CBZ) electrochemical sensor was designed by using Super-P carbon (SPCN) [email protected] ([email protected]) nanocomposite modified glassy carbon electrode ([email protected]/GCE). SPCN with pearl-chain nanostructure presented an integrated highly conductive carbon network, which significantly improved the charge transfer efficiency. ZIF-8 nanoparticles possessed high porosity and large specific surface area, which helped to realize the increasement of adsorption ability and accumulation capacity towards CBZ. Moreover, SPCN with excellent conductivity property not only inhibited the agglomeration of ZIF-8 nanoparticles but also compensated the non-conductive property of ZIF-8 nanoparticles. The functional integration of SPCN and ZIF-8 nanoparticles remarkably enhanced the electrochemical detection performance of the [email protected]/GCE sensor towards CBZ. A simple and sensitive CBZ detection could be achieved at the fabricated [email protected]/GCE sensor with low limit of detection of 7.79 nM (CBZ concentration: 0.01–30 μM). Moreover, the fabricated sensor showed good repeatability, reproducibility, and anti-interference performance. When used for the analysis of CBZ in real samples (tomato juice and apple juice), the [email protected]/GCE sensor showed good CBZ detection performance with acceptable recoveries of 99.1%–102.6% and low RSD values of 2.21%–3.27%. This work demonstrated that the [email protected]/GCE sensor may be a promising sensing platform for the rapid and sensitive detection of CBZ residue.
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