Pt@Metal–Organic Framework (ZIF-8) Thin Films Obtained at a Liquid/Liquid Interface as Anode Electrocatalysts for Methanol Fuel Cells: Different Approaches in the Synthesis

Smart membranes, nanodevices, chemical sensors, and catalytic coatings are some of the applications that make the metal-organic framework (MOF) thin films very important. Encapsulation of nanoparticles in the porous structure of MOFs can lead to the formation of effective catalysts with new unique properties and wide range of applications that may not be obtained by MOFs individually. Three main strategies, ship-in-a-bottle, bottle-around-the-ship, and in situ synthesis including the simultaneous formation of the two components, were applied for the synthesis of Pt(0)@zeolitic imidazolate framework-8 (ZIF-8) thin films at the toluene/water interface. The effects of platinum precursor transfer directions toward the interface on the properties of the films were investigated by using the [PtCl2(cod)] (where cod = cis,cis-1,5-cyclooctadiene) complex soluble in toluene as the upper phase and K2PtCl4 soluble in water as the lower phase. The six obtained films with different morphologies were applied as electrocatalysts for the methanol oxidation reaction. Considerable current density, mass activity, catalyst stability, activation energy, exchange current density, maximum power, and long-term poisoning rate are some of the advantages of the Pt(0)@ZIF-8 catalysts synthesized using the in situ strategy and K2PtCl4 as the platinum precursor. Furthermore, we report the formation of Pt@ZIF-8 nanorods at the interfaces without using any stabilizer or template. Our results suggest that the in situ strategy at the liquid/liquid interface is one of the best procedures for the synthesis of Pt(0)@ZIF-8 thin films as a suitable anode electrocatalyst for methanol fuel cells.