Performance Evaluation of Waterborne Epoxy Resin-Reinforced SBS, Waterborne Acrylate or SBR Emulsion for Road

To obtain waterborne polymer-modified emulsified asphalt materials with better comprehensive performance, waterborne polymer modifiers including waterborne epoxy resin (WER)-reinforced styrene–butadiene–styrene block copolymer (SBS), waterborne acrylate (WA) or styrene butadiene rubber (SBR) emulsion were prepared. The mechanical strength, toughness, adhesion and impact resistance of these waterborne polymers were evaluated. Furthermore, the correlation between the performance indicators of the waterborne polymers was analyzed. Based on Fourier transform infrared (FTIR) spectroscopy and thermogravimetric (TG) analysis, the mechanism of WER-modified SBS and WA was characterized. The results show that adding 10%–15% WER can significantly improve the mechanical properties of the waterborne polymer. The performances of modified SBS and WA are better than that of modified SBR. When the content of WER is 10%, the tensile strength, elongation at break and pull-off strength of WER-modified SBS and WA are 4.80–6.38 MPa, 476.3%–579.6% and 1.62–1.70 MPa, respectively. The mechanical strength and breaking energy of the waterborne polymers show a significant linear correlation with their application properties such as adhesion, bonding and impact resistance. FTIR and TG analyses indicate that WER-modified SBS or WA prepared via emulsion blending undergo primarily physical modifications, enhancing thermal stability while promoting crosslinking and curing.