Scalable construction of SiO/wrinkled MXene composite by a simple electrostatic self-assembly strategy as anode for high-energy lithium-ion batteries

Available onlineSilicon monoxide (SiO) is a promising anode material for lithium-ion batteries (LIBs) due to its high theoretical specific capacity (∼2400 mAh/g), low working potential (<0.5 V vs. Li+/Li), low cost, easy synthesis, nontoxicity, abundant natural source and smaller volume expansion than Si. However, low intrinsic electrical conductivity, low initial Coulombic efficiency (ICE) and inevitable volume expansion (∼200%) impede its practical application. Here we fabricate SiO/wrinkled MXene composite (SiO-WM) by an electrostatic self-assembly method. Importantly, this method is simple, scalable and taking into account all the issues of SiO. As a result, the SiO-WM exhibits improved rate capability, cycling performance and ICE than bare SiO.