塔菲尔方程
电催化剂
析氧
过电位
钙钛矿(结构)
材料科学
纳米颗粒
化学工程
电子转移
氧气
催化作用
纳米技术
化学
电极
电化学
光化学
物理化学
生物化学
工程类
有机化学
作者
Xiaoping Gao,Zhimin Sun,Jiaqi Ran,Jufu Li,Jingyan Zhang,Daqiang Gao
标识
DOI:10.1038/s41598-020-70283-9
摘要
Abstract Due to the multistep proton-coupled electron transfer, it remains a huge challenge to accelerate the kinetics of oxygen evolution reaction (OER). Here, we demonstrate that perovskite-type LaCr 0.5 Fe 0.5 O 3 nanoparticles can be used as highly active and stable OER electrocatalysts, where it shows a low overpotential of 390 mV at 10 mA/cm 2 , a small Tafel slope of 114.4 mV/dec and excellent stability with slight current decrease after 20 h, superior than that of their individual counterparts (LaFeO 3 and LaCrO 3 ). This finding confirms that the present hybrid material would be an effective means to electrocatalyst for catalyzing OER.
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