材料科学
光催化
可见光谱
紫外线
化学工程
二氧化钛
氧气
纳米尺度
纳米技术
钛酸酯
光化学
光电子学
复合材料
催化作用
陶瓷
有机化学
化学
工程类
生物化学
作者
Hengcheng Wan,Ling Zhang,Yi Li,Qi Meng,Youkui Zhang,Tao Duan
出处
期刊:Nanotechnology
[IOP Publishing]
日期:2021-04-20
卷期号:32 (28): 285601-285601
被引量:1
标识
DOI:10.1088/1361-6528/abbf69
摘要
Increasing photoactive areas and oxygen vacancy to improve the separation and utilization of electrons and holes in a photocatalytic process are a guarantee for highly photocatalysis efficiency. In this work, we report a CAs@B-TiO2core-shell nanospheres via a nanoscale water spray assisted method to deposit of black titanium dioxide (B-TiO2) on carbon aerogel sphere (CAs) though slowly hydrolyzing of butyl titanate (e.g. TBOT) in an ethanol-water system. On this basis, furthermore, a facile one-step N2H4 · H2O treatment was used to introduces oxygen vacancies on the surface of TiO2coating layer forming black TiO2. Oxygen vacancies can extend the optical response range of the TiO2shell from the ultraviolet to the visible region, and increase conductivity and charge transport on the interface of core-shell structure. This study reveals the importance of surface oxygen vacancies for reducing band gaps and developing highly active photocatalysts under visible light.
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