MCPA公司
化学
溶解有机碳
腐殖质
有机质
环境化学
腐植酸
堆肥
疏水效应
有机化学
土壤水分
杀虫剂
农学
土壤科学
生物
肥料
环境科学
作者
Dongming Wu,Changqi Ren,Lei Jiang,Qinfen Li,Wen Zhang,Chunyuan Wu
标识
DOI:10.1016/j.scitotenv.2020.138262
摘要
Dissolved organic matter (DOM) is ubiquitous with high biological and chemical activity. The large intake of DOM from compost, plant residues or soil can modify the behaviors of agrochemicals. Phenoxy herbicide is the third widely used herbicide around the world with both aromaticity and polarity. However, how the diverse fractions of DOM interacting with phenoxy herbicide and the underlying mechanisms remain unknown. Thus, it is crucial to investigate the heterogeneous chemical properties of DOM fractions from variable sources and explore the interactive mechanisms. In this study, polar DOM derived from compost, rice straw and soil were fractionated, and the chemical properties of fractions were analyzed by spectrum technology and the complex interaction with phenoxy herbicide was assessed by infrared spectroscopy. Results showed that hydrophobic acid (HOA) was the largest component (49.6%) in compost DOM, while hydrophilic matter (HIM) was the main component in the polar DOM from rice straw and soil. The 4-chloro-2-methylphenoxyac etic acid (MCPA) as one representative of phenoxy herbicides was used in our study, and the results showed the interaction between different DOM fractions and MCPA was heterogeneous. HOA containing abundant fulvic-like component and polar groups resulted a greatly complex interaction with MCPA mainly via hydrophobic force, ligand exchange and hydrogen bonding. Hydrophobic neutral fraction and acid-insoluble matter showed a medium interaction with MCPA as a result of enrichment with the high aromatic humic-like molecules. Inversely, no significant interaction between HIM and MCPA was observed. Our research revealed that the aromatic framework associated with polar groups in DOM dominated the interaction with phenoxy herbicide, which might affect the bioavailability, toxicity, and mobility of phenoxy herbicide.
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