锐钛矿
材料科学
纳米管
化学工程
钛酸酯
基础(拓扑)
盐(化学)
转化(遗传学)
纳米技术
无机化学
化学
有机化学
复合材料
碳纳米管
催化作用
光催化
工程类
陶瓷
数学分析
基因
生物化学
数学
作者
Chien Cheng Tsai,Hsisheng Teng
摘要
We demonstrated that nanotubes synthesized from a NaOH treatment on TiO2 with subsequent acid washing could proceed with repeatable crystalline-structure transformation through a simple acid−base washing step. By providing the unit cell parameters, we identified a divalent salt titanate (Na2Ti2O5·H2O) with a layered structure as the structure formed after the NaOH treatment. With the increase in acidity during the post-treatment acid washing, the layered titaniate transformed into a nanotube through Na+−H+ substitution, and eventually transformed into anatase TiO2. Crystalline-structure analysis has shown the feasibility of this titanate−titania transformation occuring through a simple structural rearrangement. A complete scheme for the formation and transformation of nanotubes induced by the NaOH treatment and the post-treatment washing was proposed.
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