材料科学
电化学
阳极
电极
阴极
纳米技术
储能
卟啉
有机化学
化学
量子力学
物理
物理化学
功率(物理)
作者
Zhirong Zhao‐Karger,Ping Gao,Thomas J. Ebert,Svetlana Klyatskaya,Zhi Chen,Mario Rüben,Maximilian Fichtner
标识
DOI:10.1002/adma.201806599
摘要
Organic materials are both environmentally and economically attractive as potential electrode candidates. This Research News reports on a new class of stable and electrically conductive organic electrodes based on metal porphyrins with functional groups that are capable of electrochemical polymerization, rendering the materials promising for electrochemical applications. Their structural flexibility and the unique highly conjugated macrocyclic structure allows the produced organic electrodes to act as both cathode and anode materials giving access to fast charging as well as high cycling stability. The extreme thermal and chemical stability of the porphyrin-based organic electrodes and their chemical versatility suggest an important role for these molecular systems in the further development of novel electrochemical energy storage applications.
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