噻吩
共轭体系
分子内力
吡啶
单体
电化学
光化学
共聚物
荧光
兴奋剂
吸收光谱法
化学
电子转移
吸收(声学)
材料科学
高分子化学
聚合物
有机化学
物理化学
光电子学
电极
光学
物理
复合材料
作者
Zhenhua Zhou,Tsukasa Maruyama,Takaki Kanbara,Tomiki Ikeda,Kunihiro Ichimura,Takakazu Yamamoto,Koichi Tokuda
出处
期刊:Journal of the Chemical Society
[The Royal Society of Chemistry]
日期:1991-01-01
卷期号: (17): 1210-1212
被引量:71
摘要
Electrically conducting π-conjugated copolymers consisting of π-excessive thiophene-2,5-diyl and π-deficient pyridine-2,5-diyl monomer units show a unique cyclic voltammogram with an unusually large potential difference between the doping and the undoping peaks, and their electronic and fluorescence spectra support occurrence of intramolecular charge transfer showing absorption and fluorescence peaks at lower energy compared with those of the corresponding homopolymers.
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