丁香酚
解聚
单体
苯酚
木质素
聚合物
有机化学
聚合
化学改性
生物高聚物
高分子科学
化学
材料科学
高分子化学
作者
Roberto Morales‐Cerrada,Samantha Molina-Gutiérrez,Patrick Lacroix‐Desmazes,Sylvain Caillol
出处
期刊:Biomacromolecules
[American Chemical Society]
日期:2021-08-31
卷期号:22 (9): 3625-3648
被引量:124
标识
DOI:10.1021/acs.biomac.1c00837
摘要
Biobased materials, derived from biomass building blocks, are essential in the pursuit of sustainable materials. Eugenol, a natural phenol obtained from clove oil, but also from lignin depolymerization, possesses a chemical structure that allows its easy modification to obtain a broad and versatile platform of biobased monomers. In this Perspective, an overview of the variety of reactions that have been executed on the allylic double bond, phenol hydroxyl group, aromatic ring, and methoxy group is given, focusing our attention on those to obtain monomers suitable for different polymerization reactions. Furthermore, possible applications and perspectives on the eugenol-derived materials are provided.
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