纳米材料基催化剂
催化作用
纳米颗粒
铜
材料科学
反应性(心理学)
贵金属
化学工程
多孔性
金属
聚合物
选择性催化还原
金属有机骨架
反应速率常数
无机化学
化学
纳米技术
有机化学
动力学
冶金
复合材料
吸附
量子力学
医学
替代医学
病理
工程类
物理
作者
Fariba Rezaei,Mohammad Dinari
标识
DOI:10.1016/j.micromeso.2021.111339
摘要
The improvement of effective catalytic systems relies on the synthesis of catalytically active composites including metal nanocatalysts and porous supports. In particular, it is essential to develop porous composites comprising cheaper metal nanocatalysts rather than expensive noble metals. This study reports the preparation of covalent organic polymer (COP) as a support in the immobilization of Cu nanoparticles (NPs). Cu(II) species were successfully chelated to nitrogen and oxygen atoms in the COP by mixing with a copper (II) acetate solution. The as-prepared catalysts were distinguished using various methods, including XRD, FE-SEM, FT-IR, BET, EDX, and ICP-AES. The findings indicated that uniform Cu NPs were homogeneously and firmly embedded into the surface of COP. The final Cu–COP sample demonstrated efficient catalytic activity in the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP). The activity factor (k') and rate constant (Kapp) of Cu–COP were respectively 9.65 s−1 and 0.0193 s−1 g−1 for 4-NP reduction and could completely transform 4-NP to 4-AP within 3 min. Furthermore, the conversion rate of the supported nanoparticles was 97.1% in 4-NP reduction up to five cycles with no decreased reactivity.
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