化学
串联
催化作用
过氧化氢
水溶液
甲烷氧化偶联
氧化磷酸化
光化学
组合化学
有机化学
生物化学
复合材料
材料科学
作者
Muhammet Uyanik,Dai Nagata,Kazuaki Ishihara
摘要
We report the hypoiodite-catalyzed oxidative C-C homocoupling of arenols to biarenols or biquinones using aqueous hydrogen peroxide as an oxidant. In addition, by combining hypoiodite catalysis and lipophilic Lewis acid-assisted Brønsted acid catalysis under aqueous conditions, we achieved a tandem oxidation/cross-coupling reaction of hydroquinones with electron-rich arenes. These results highlight the substantial scope of hypoiodite/acid co-catalysis for use in oxidative coupling reactions.
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