Flower-like NiCo2S4/NiFeP/NF composite material as an effective electrocatalyst with high overall water splitting performance

Rational design and building of high efficiency, secure and inexpensive electrocatalyst is a pressing demand and performance to promote sustainable improvement of hydrogen energy. The bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen evolution response (HER) with high catalytic performance and steadiness in the equal electrolyte are extra treasured and meaningful. Herein, a unique three-dimensional (3D) structure electrocatalyst for NiCo 2 S 4 growing on the flower-like NiFeP was designed and synthesized in this study. The results show that the flower-like NiCo 2 S 4 /NiFeP/NF composite electrocatalyst has large specific surface area, appropriate electrical conductivity, and greater lively websites uncovered in the three-dimensional structure, and affords extraordinary electrocatalytic overall performance for the ordinary water splitting. In alkaline solution, the OER and HER overpotentials of NiCo 2 S 4 /NiFeP/NF only need 293 mV and 205 mV overpotential to provide the current densities of 100 mA/cm 2 and 50 mA/cm 2 , respectively. This high electrocatalytic activity exceeds the catalytic activity of most nickel-iron based electrocatalysts for OER and HER process. Accordingly, the optimized NiCo 2 S 4 /NiFeP/NF sample has higher stability (24 h) at 1.560 and 10 mA/cm 2 , which extensively speeds up the overall water splitting process. In view of the above performance, this work offers a fine approach for the further improvement of low fee and excessive effectivity electrocatalyst. A facile strategy is developed to synthesize three-dimensional flower-like NiCo 2 S 4 /NiFeP/NF bifunctional electrocatalyst. Using commercially available solar cells (about 2 V) for NiCo 2 S 4 /NiFeP/NF||NiCo 2 S 4 /NiFeP/NF cell power supply, and the continuous evolution of H 2 and O 2 bubbles in the two electrodes.