High-index faceted metal oxide micro-/nanostructures: a review on their characterization, synthesis and applications

Exposed high-index facets with a high density of low-coordinated atoms (including edges, steps and kinks) can provide more high-active sites for chemical reactions. Therefore, great progress has made in the facet-dependent application of various high-index faceted micro-/nanostructures in the past decades. Previous review papers have mainly highlighted the advances in high-index faceted noble metal nanocrystals. However, to date, there is no specialized review paper on high-index faceted metal oxides and their facet-dependent applications. Thus, in this review, the existing high-index faceted metal oxide micro-/nanostructures, including Cu2O, TiO2, Fe2O3, ZnO, SnO2 and BiVO4, are reviewed based on their characterization, synthesis engineering and facet-dependent applications in the fields of catalysis, sensors, lithium-ion batteries and carbon monoxide oxidation. Also, several challenges and perspectives are presented. Hopefully, this review article will be a useful guideline and resource for researchers currently concentrating on high-index faceted metal oxides to design and synthesize novel micro-/nanostructures for overcoming the practical environment-, biology- and energy-related problems.