吸热过程
水溶液
化学
十二烷基苯磺酸钠
焓
放热反应
四氟硼酸盐
三元运算
相图
热力学
等温微量热法
相(物质)
双水相体系
三元数制
等温过程
离子液体
无机化学
物理化学
有机化学
吸附
催化作用
程序设计语言
物理
计算机科学
作者
Qi Liu,Xiaoxiao Chen,Yanan Guo,Chuanhong Han,Jing Li,Lihan Jia,Jie Liu,Xilian Wei
标识
DOI:10.1016/j.molliq.2019.01.118
摘要
A ternary phase diagram of the system of 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4), sodium dodecylbenzenesulfonate (SDBS) and water using ocular estimate and turbidity method was drawn based on experimental data at 298.2 K. We got a narrow aqueous two-phase region near the side of water-ionic liquid (IL). A series of samples with different compositions around the phase diagram were chosen. The enthalpy change of these systems after injecting triply distilled water into these samples has been studied by using isothermal titration microcalorimetry (ITC). It is found that with increasing the water content there are weak endothermic and exothermic processes appearing, separately, which matches perfectly with the location of the formation and disappearance of the aqueous two-phase in the ternary phase diagram. This suggests the ITC is a feasible and effective method for the thermodynamic study of aqueous two-phase systems (ATPS) and was first reported. The experimental results show that the formation of the ATPS is endothermic (ΔH > 0), but the process of disappearing is exothermic (ΔH < 0). Due to the formation of aqueous two-phase is a thermodynamic spontaneous process under the isothermal constant pressure, we can judge that the formation of this ATPS is an entropy driven course and the vanishing is a synergy driven process by entropy and enthalpy.
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