吸附
自愈水凝胶
木质素
化学
衣康酸
朗缪尔吸附模型
亚甲蓝
丙烯酸
化学工程
马来酸酐
甲基丙烯酸酯
高分子化学
有机化学
核化学
聚合物
共聚物
工程类
光催化
催化作用
作者
Shuo Wang,Xu Chen,Yida Yin,Hao Meng,Yonggui Wang,Zefang Xiao,Haigang Wang,Daxin Liang,Yanjun Xie
标识
DOI:10.1016/j.indcrop.2022.115840
摘要
Dye removal from wastewater via adsorption constitutes an active area of research in effluent treatment. For this purpose, superadsorbent hydrogels have emerged as a promising tool; however, large adsorption capacities for various dyes are still required. As a novel adsorbent, lignin is attracting attention owing to its abundant sources and environmental friendliness; unfortunately, its hydrophobicity limits its practical application. Herein, lignin was directly esterified using methacrylate anhydride, itaconic anhydride, or maleic anhydride to produce three lignin esters (LEs) with different hydrophilic properties. These LEs were subsequently used to copolymerize with acrylic acid, yielding three types of hydrogels. Because of high water-absorbing capacity of hydrogels, the highest adsorption capacity reported to date for methylene blue was obtained (2445 mg g−1) using lignin-based adsorbents. The type of LEs, the reactant concentrations and ratios, and the pH of the soaking solution affected the properties and hence the adsorption capacities of the hydrogels. The adsorption process was fitted with a pseudo-second-order model and the Langmuir adsorption isotherm model. This study reveals the synergistic adsorptive action of lignin and confirms the potential of LE–acrylic acid hydrogels for removing methylene blue from sewage.
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