发射率
材料科学
电致变色
光电子学
红外线的
非阻塞I/O
电致变色装置
光学
低发射率
可见光谱
电极
化学
物理
生物化学
物理化学
催化作用
作者
Wanxin Sun,Xiang Zhang,Mingjun Chen,Jie Deng,Hulin Zhang,Zitong Li,Yingjun Xiao,Liping Hu,Dukang Yan,Yao Li
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2023-12-08
卷期号:6 (24): 23506-23514
标识
DOI:10.1021/acsanm.3c04872
摘要
Dual-band electrochromic coupling is a phenomenon in which an electrochromic material can modulate the visible and infrared (IR) light spectra simultaneously. Due to their coupling of visible and IR wavelengths, high solar absorptivity, and low IR emissivity modulation, the application of all-solid-state electrochromic devices (ECDs) to space technology has become a great challenge. Here, a nanomultilayer optical simulation structure of ECDs was built to solve the above problem. In this study, the IR emissivity of ECDs (F–P ECDs) with a nanostructure of Au/NiO/Ta2O5/WO3/Ge is studied in detail via a Fabry–Perot resonance. The result shows that the IR emissivity regulating the ability of F–P ECDs is approximately 0.53 in the spectral range of 2–14 μm, with a maximum of 0.62 at 9.8 μm. To improve the IR emissivity modulation ability and solar radiation reflectivity as much as possible, a metamaterial structure (alternating deposition of ZnS and YbF3) is applied to F–P ECDs. The nanostructure, Au/NiO/Ta2O5/WO3/Ge/Metamaterials (M-ECDs), is studied in detail. The results show that the IR emissivity modulation of M-ECDs is approximately 0.72 in the spectral range of 2–14 μm, with a maximum of 0.87 at 10.5 μm. At the same time, M-ECDs can reflect 90.5% of solar radiation in the spectral range of 300–1500 nm. On the basis of these results, it is believed that the Fabry–Perot resonance and metamaterials provide a promising opportunity for future space technology.
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