材料科学
无定形固体
锂(药物)
氧气
离子
异质结
光电子学
纳米技术
结晶学
医学
化学
物理
有机化学
量子力学
内分泌学
作者
Ziwei Yan,Kehua Zhu,Haidi Xu,Shiqiang Wei,Wen Wen,Changda Wang,Li Song
标识
DOI:10.1002/adfm.202402543
摘要
Abstract Due to the long‐range atomic disorder and more active sites, amorphous MXenes with better chemical reactivity and electrical conductivity, have attracted wide attention in energy storage devices. However, to reach the practical applications of MXenes, investigations into the best structure of the amorphous layer are essential. Here, the structure evolution of MXenes induced from ammonium persulfate is explored via synchrotron radiation X‐ray absorption spectroscopy. Then, a kind of oxygen‐poor amorphous heterojunction Nb 2 CT x MXene (a‐Nb 2 CT x ) is designed. Benefitting from the oxygen‐poor amorphous heterojunction, the a‐Nb 2 CT x electrode exhibits excellent Li + storage performance with a high discharge specific capacity of 382 mAh g −1 at 0.1 A g −1 and a long cycling stability of 300 mAh g −1 at 1.0 A g −1 after 800 cycles. Operando synchrotron X‐ray diffraction results reveal that oxygen‐poor amorphous heterojunction stabilizes Nb 2 CT x MXene from undergoing structural changes during cycling. This work provides new insights into the rational design of novel amorphous MXenes, which is of great significance for the development of MXenes and their applications in high‐performance energy storage systems.
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