化学
丙胺
非对映体
药物化学
立体化学
有机化学
胺气处理
作者
L. De Buyck,Chiara Danieli,Franco Ghelfi,U. M. Pagnoni,Andrew F. Parsons,Mariella Pattarozzi,Fabrizio Roncaglia
出处
期刊:Tetrahedron
[Elsevier]
日期:2005-03-01
卷期号:61 (11): 2871-2877
被引量:17
标识
DOI:10.1016/j.tet.2005.01.086
摘要
The rearrangement of a trichloro-pyrrolidin-2-one, prepared by the CuCl–TMEDA catalyzed atom transfer radical cyclization of N-alkyl-N-(3-chloro-2-propenyl)-2,2-dichloromyristamide, with n-propylamine or CH3ONa/CH3OH, is the key step of a new, short and inexpensive route to chaetomellic anhydride C and (±)-erythro-roccellic acid.
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