氯化亚砜
锂(药物)
交换电流密度
阳极
氯化锂
化学
电化学
分析化学(期刊)
电化学电池
氯化物
动能
无机化学
电极
物理化学
物理
色谱法
有机化学
塔菲尔方程
内分泌学
医学
量子力学
摘要
A 1-D math model for the lithium/thionyl chloride primary cell is used in conjunction with a parameter estimation technique in order to estimate the electro-kinetic parameters of this electrochemical system. The electro-kinetic parameters include the anodic transfer coefficient and exchange current density of the lithium oxidation, alpha sub a,1 and i sub o,i,ref, the cathodic transfer coefficient and the effective exchange current density of the thionyl chloride reduction, alpha sub c,2 and a sup o i sub o,2,ref, and a morphology parameter, Xi. The parameter estimation is performed on simulated data first in order to gain confidence in the method. Data, reported in the literature, for a high rate discharge of an experimental lithium/thionyl chloride cell is used for an analysis.
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