During uncompensable occupational heat stress, heat-mitigation controls are required to prevent core temperature exceeding recommended limits (≥38 °C). However, the initial stay time before employing controls remained unknown. We estimated these times for moderate-intensity work at 26, 28, 30, and 32 °C wet-bulb globe temperatures (WBGT) in 50 young (18–30 years) and older (50–70 years), non-heat acclimatized men. Initial stay time was 111 min at 26 °C WBGT and declined exponentially to 44 min at 32 °C WBGT. Novelty: We provide estimates of the moderate-intensity work duration before heat-mitigation is required in wet-bulb globe temperatures between 26–32 °C for young and older, non-heat acclimatized men.