成核
化学
过电位
铜
电流密度
饱和(图论)
交换电流密度
玻璃碳
电流(流体)
电极
热力学
化学物理
电化学
物理化学
循环伏安法
有机化学
塔菲尔方程
物理
组合数学
量子力学
数学
作者
Theodora Zapryanova,A. Hrussanova,A. Milchev
标识
DOI:10.1016/j.jelechem.2006.10.002
摘要
The nucleation and growth of copper crystals on a glassy carbon electrode are investigated at different constant overpotentials. Current transients are recorded and the number of copper nuclei is microscopically registered. The experimental data for the growth current are interpreted according to the theories of progressive and instantaneous nucleation and information is obtained on the stationary nucleation rate, the saturation nucleus number density and the exchange current density at the crystals–solution interface boundary.
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