化学
酞菁
离域电子
二聚体
电子顺磁共振
光化学
未成对电子
高分子化学
有机化学
核磁共振
分子
物理
标识
DOI:10.1142/s1088424613500880
摘要
The first push-pull μ-nitrido diiron phthalocyanine complex was prepared and characterized. The EPR spectrum confirms the Fe +3.5 – N – Fe +3.5 formalism. The stability of this dimer in oxidant media (up to 1000 equivalent of H 2 O 2 ) was studied by UV-vis spectroscopy. The push-pull μ-nitrido diiron phthalocyanine exhibited excellent stability because of the delocalization of an unpaired electron.
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