发光
吸光度
水溶液中的金属离子
材料科学
猝灭(荧光)
离子
金属
光化学
金属有机骨架
发光测量
无机化学
化学
纳米技术
荧光
分析化学(期刊)
化学物理
光电子学
物理化学
吸附
有机化学
光学
色谱法
物理
冶金
作者
Meng Wang,Lin Guo,Dapeng Cao
标识
DOI:10.1016/j.snb.2017.10.016
摘要
The luminescence turn-on sensors are more suitable for the practical applications, because they can effectively avoid the wrong response and have a higher signal-to-noise in dark background, compared to the luminescent quenching probes. In this work, we use IRMOF-3 as a luminescent probe to systematically investigate its sensing behavior for detecting metal ions. By examining the relationship of absorbance and luminescent intensity of IRMOF-3 before and after adding metal ions, we propose a novel luminescence turn-on mechanism, i.e., absorbance caused enhancement (ACE) mechanism, to reveal the luminescence turn-on phenomena of IRMOF-3 for selectively sensing M3+ (Cr3+, Al3+, Ga3+, In3+) metal ions. By exploring the effects of M3+ ion concentrations on absorbance and luminescent intensity, we further confirm the ACE mechanism responsible for luminescence turn-on phenomena. The subsequent experimental results indicate that IRMOF-3 exhibits not only high sensitivity and anti-interference ability against M2+ and M+ metal ions, but also have excellent reusability and stability. In short, the ACE mechanism provides a possible strategy for designing luminescence turn-on probes.
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