催化作用
过硫酸盐
化学
激进的
降级(电信)
二硫化钼
反应速率常数
污染物
光化学
化学工程
有机化学
动力学
计算机科学
工程类
物理
电信
量子力学
作者
Shanhao Li,Xueer Ning,Pingyu Hao,Yali Cao,Jing Xie,Jindou Hu,Zhenjiang Lu,Aize Hao
标识
DOI:10.1016/j.dyepig.2022.110678
摘要
Piezocatalytic technology opens a new avenue in driving green catalysis processes by harvesting mechanical energy, but the catalytic activity is still far from satisfying. In this work, defect-rich molybdenum disulfide (DR-MoS2) piezocatalyst was prepared and explored piezocatalytic activation peroxymonosulfate (PMS) performance towards degradation of organic pollutant (RhB dye) under ultrasonic vibration (US) condition. DR-MoS2/PMS/US system exhibits an excellent catalytic activity such as high degradation efficiency (∼92.1% after 25 min), large kinetic rate constant (0.09533 min−1) as well as good stability, far surpassing most of the reported other piezocatalyst systems. Particularly, degradation kinetic rate constant of DR-MoS2/PMS/US system is over 13 and 3 times than that of single normal MoS2 values under US and US/PMS conditions, respectively. The outstanding catalytic activity in DR-MoS2/PMS/US system is mainly ascribed to the strong synergistic effect between piezocatalysis and PMS as well as electrochemical reaction in catalytic process. More importantly, hydroxyl radicals (·OH), sulfate radicals (SO4˙−) and superoxide radicals (·O2−) are primary reactive oxygen species in piezocatalytic activation PMS process towards RhB degradation. Furthermore, we further clarify the possible piezocatalytic mechanism in DR-MoS2/PMS/US system towards RhB degradation. This work not only extends the application of piezocatalysis, but also offers beneficial guidance towards high-efficiency mechanically activated persulfate in sustainable wastewater remediation.
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