Achieving Record External Quantum Efficiency of 11.5 % in Solution‐Processable Deep‐Blue Organic Light‐Emitting Diodes Utilizing Hot Exciton Mechanism

Abstract High performance solution‐processable deep‐blue emitters with a Commission International de l′Eclairage (CIE) coordinate of CIE y ≤0.08 are highly desired in ultrahigh‐definition display. Although, deep‐blue materials with hybridized local and charge‐transfer (HLCT) excited‐state feature are promising candidates, their rigidity and planar molecular structures limit their application in solution‐processing technique. Herein, four novel deep‐blue solution‐processable HLCT emitters were first proposed by attaching rigid imide aliphatic rings as functional units onto the HLCT emitting core. The functional units not only improve solubility, enhance thermal properties and morphological stability of the emitting core, but also promote photoluminescence efficiency, balance charge carrier transport, and inhibit aggregation‐caused quenching effect due to the weak electron‐withdrawing property as well as steric hindrance. The corresponding solution‐processable organic light‐emitting diodes (OLEDs) substantiate an unprecedented maximum external quantum efficiency (EQE max ) of 11.5 % with an emission peak at 456 nm and excellent colour purity (full width at half maximum=56 nm and CIE y =0.09). These efficiencies represent the state‐of‐the‐art device performance among the solution‐processable blue OLEDs based on the “hot exciton” mechanism. This simple strategy opens up a new avenue for designing highly efficient solution‐processable deep‐blue organic luminescent materials.