A new strategy to improve the dielectric properties of cellulose nanocrystals (CNCs): Surface modification of small molecules

Nanocellulose finds various applications in advanced electrical devices due to its impressive mechanical properties, thermal stability, and degradability. Cellulose nanocrystals (CNCs) with excellent dielectric properties may act as a fresh dielectric plastic. In this study, a new strategy of small molecule modification was used to improve the dielectric constant, breakdown strength, and band gap of the CNCs. The dipole moments, dipole density, and the anisotropic impact of surface groups on the dielectric constant were studied. The number of sulfates in the CNCs showed a gradient due to alkali treatment and sulfonation, which allowed for a controlled range of the dielectric constant of nanocellulose between 4.9 and 11.9. TEMPO oxidation (2,2,6,6-tetramethylpiperidine-1-oxyl) and cyanoethylation of the CNCs further increased the dielectric constant to 11.1 and 13.2, respectively, and the dielectric loss 10−1. By understanding and innovating organic polymer dielectrics, we can provide significant benefits to the electronics and device industries.