光催化
光降解
降级(电信)
光化学
氮化碳
碳纤维
化学
石墨氮化碳
反应速率常数
氮化物
材料科学
动力学
有机化学
催化作用
复合材料
计算机科学
物理
复合数
电信
图层(电子)
量子力学
作者
Yunxiong Zeng,Xingyu Zhan,Bo Hong,Yingchun Xia,Yangbin Ding,Tao Cai,Ke Yin,Xingqin Wang,Liming Yang,Shenglian Luo
标识
DOI:10.1016/j.cej.2022.139434
摘要
Recently, antibiotic pollution has aroused great concern due to its toxicity to living organisms and the risk of drug-resistance gene generation in the ecosystem. Carbon nitride (CN) photodegradation towards antibiotics is a promising technology for water purification. However, CN possesses a low activity due to the fast recombination of electron-hole pairs and slow reaction kinetics. Herein, we report the fabrication of nitrogen-vacancy and oxygen-substitution modified carbon nitride ((Nv, Os)–CN) with a rearranged surface via a low-temperature thermal oxidation strategy. The (Nv, Os)–CN can degrade tetracycline (TC), ciprofloxacin (CIP) and sulfadiazine (SZO) than CN under visible light irradiation efficiently. The first-order kinetic constant of (Nv, Os)–CN for TC, CIP and SZO was 2.1, 2.24 and 1.38 folds higher than those of CN, respectively. This high performance benefits from the rearranged surface atoms by forming an active surface with rich Nv and Os, thus promoting interfacial charge transfer and building robust water-(Nv, Os)–CN interface. In addition, the possible photodegraded pathways, resulting intermediates and risks of TC photodegradation were analyzed by the LC-MS and QSAR methods. Our proposed low-temperature thermal oxidation strategy to achieve surface atom rearrangement endows CN with an enhanced photoactivity toward antibiotics degradation.
科研通智能强力驱动
Strongly Powered by AbleSci AI