光催化
选择性
兴奋剂
催化作用
材料科学
过渡金属
金属
光化学
量子点
纳米技术
俘获
可见光谱
光电子学
电子
化学
物理
有机化学
冶金
生物
量子力学
生态学
作者
Jin Wang,Xia Tong,Lei Wang,Xusheng Zheng,Zeming Qi,Chao Gao,Junfa Zhu,Zhengquan Li,Hangxun Xu,Yujie Xiong
标识
DOI:10.1002/anie.201810550
摘要
Abstract Quantum dots (QDs), a class of promising candidates for harvesting visible light, generally exhibit low activity and selectivity towards photocatalytic CO 2 reduction. Functionalizing QDs with metal complexes (or metal cations through ligands) is a widely used strategy for improving their catalytic activity; however, the resulting systems still suffer from low selectivity and stability in CO 2 reduction. Herein, we report that doping CdS QDs with transition‐metal sites can overcome these limitations and provide a system that enables highly selective photocatalytic reactions of CO 2 with H 2 O (100 % selectivity to CO and CH 4 ), with excellent durability over 60 h. Doping Ni sites into the CdS lattice leads to effective trapping of photoexcited electrons at surface catalytic sites and substantial suppression of H 2 evolution. The method reported here can be extended to various transition‐metal sites, and offers new opportunities for exploring QD‐based earth‐abundant photocatalysts.
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