Development of electric/near-infrared light-driven shape memory rGO/EVA composite films for deployable structures

Purpose This study aims to fabricate the reduced graphene oxide (rGO)/ethylene vinyl acetate copolymer (EVA) composite films with electric-driven two-way shape memory properties for deployable structures application. The effect of dicumyl peroxide (DCP) and rGO on the structure and properties of the rGO/EVA composite films were systematically investigated. Design/methodology/approach The rGO/EVA composite films were fabricated by melting blend and swelling-ultrasonication method, DCP and rGO were used the crosslinking agent and conductive filler, respectively. Findings The research results indicate that the two-way shape memory properties of rGO/EVA composite films were significantly improved with the increase of DCP content. The rGO endowed rGO/EVA composite films with excellent electric-driven reversible two-way shape memory and anti-ultraviolet aging properties. The sample rGO/EVA-9 can be heated above Tm within 8 s at a voltage of 35 V and can be heated above the Tm temperature within 12 s under near-infrared light (NIR). Under a constant stress of 0.07 MPa, the reversible strain of the sample rGO/EVA-9 was 8.96% and its electric-driven shape memory behavior maintained great regularity and stability. Research limitations/implications The rGO/EVA composite films have potential application value in the field of deployable structures. Originality/value With the increase of DCP content, the two-way shape memory properties of rGO/EVA composite films were significantly improved, which effectively solved the problem that the shape memory properties of EVA matrix decreased caused by swelling. The rGO endowed rGO/EVA composite films with excellent electric/NIR driven reversible two-way shape memory properties.