铋
检出限
金属有机骨架
电化学
吸附
电极
材料科学
介孔材料
碳纤维
电化学气体传感器
化学
核化学
复合材料
色谱法
冶金
有机化学
物理化学
复合数
催化作用
作者
Qiuyu Yang,Sun Xiu-Li,Yang Sun,Xiaofang Shen,Yuehong Pang
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2023-05-03
卷期号:6 (9): 7901-7909
被引量:4
标识
DOI:10.1021/acsanm.3c01096
摘要
An amino-functionalized bismuth metal–organic framework (Bi-BDC-NH2) composited with nitrogen-doped mesoporous carbon nanosphere (NMCS) was prepared to fabricate a Bi-BDC-NH2@NMCS electrochemical sensor for simultaneous determination of Pb(II) and Cd(II). The synthesized Bi-BDC-NH2 was granular, amorphous, and loosely aggregated to form a porous structural composition where NMCS was embedded. The large specific area and exposed sites of Bi-BDC-NH2@NMCS copromote the adsorption and electron transfer of metal ions on the electrode surface. Compared with the traditional bismuth film electrode, the Bi-BDC-NH2@NMCS electrode can improve the charge transfer, stability, and conductivity. The developed method exhibited superior stripping performance with a detection limit of 0.36 ng mL–1 for Pb(II) and 0.44 ng mL–1 for Cd(II), respectively, and a linear range of 1.0–1500 ng mL–1. It was applied to detect Pb(II) and Cd(II) in liver, fish, and shrimp samples with recoveries of 93.6–99.7% and 94.4–103.2%, respectively.
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