光子上转换
离子
材料科学
发光
激发
壳体(结构)
芯(光纤)
能量转移
分析化学(期刊)
光电效应
纳米技术
化学
光电子学
化学物理
物理
有机化学
色谱法
量子力学
复合材料
作者
Wei Gao,Binhui Chen,Shanshan Han,Xingchao Wang,Yingbin Xing,Qingyan Han,Xuewen Yan,Chengyun Zhang,Jun Dong
标识
DOI:10.1016/j.optmat.2023.114137
摘要
In this work, the energy transfer process and upconversion luminescence properties of NaYF4: Ln3+@NaYF4: Ln3+ (Ln = Yb3+, Er3+, Tm3+) core-shell microcrystals were studied through introducing different Yb3+ ions in core and shell. Compared with Yb3+/Tm3+/Er3+ co-doped NaYF4 microcrystals, the NaYF4:Yb3+/Tm3+@NaYF4: Yb3+/Er3+ core-shell microcrystals displays greater stability spectral characteristics under NIR 980 nm excitation. This is because the core-shell structures can control the excitation energy acquisition channel and avoid interactions between Er3+ and Tm3+ ions. Meanwhile, the luminescence properties of NaYF4@NaYF4 core-shell microcrystals can also be precisely controlled by changing concentrations of Yb3+ ions in the core and shell, respectively. The experimental results further indicate that upconversion emission of microcrystals can also be precisely controlled by constructing core-shell structures. The multicolor emission core-shell microcrystals may have great potential in display, anti-counterfeiting and micro-photoelectric technology applications.
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