化学
试剂
催化作用
组合化学
基质(水族馆)
范围(计算机科学)
级联
有机合成
激进的
自由基环化
有机化学
立体化学
海洋学
色谱法
计算机科学
程序设计语言
地质学
作者
Zhuangzhuang Guo,Xiaoyu Chen,Yingying Xue,jingya Li,Dapeng Zou,Yangjie Wu,Yusheng Wu
标识
DOI:10.1002/adsc.202200854
摘要
Abstract A copper‐catalyzed cascade difunctionalization of unactivated olefins with readily available R f ‐I reagents to construct C sp 3 −CF 2 /C−C bonds has been reported. This strategy provides a convenient access to a variety of useful perfluoroalkylated tricyclimidazole derivatives in reasonable yields. Preliminary mechanistic studies indicate that the present reaction probably undergo a radical/SET (single electron transfer) pathway. The transformation features mild condition, simple operation, atomic economy, and broad substrate scope. magnified image
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