光催化
莫来石
可见光谱
布朗斯特德-洛瑞酸碱理论
材料科学
化学工程
化学
光化学
矿物学
催化作用
光电子学
复合材料
有机化学
陶瓷
工程类
作者
Chenyang Xiao,Guohui Dong,Takafumi Yao,Heyou Han,Ting Dong,Tong Zhou
标识
DOI:10.1016/j.apsusc.2024.159453
摘要
Clay minerals are considered promising semiconductor carrier materials due to their unique physical and chemical properties. However, the exact mechanism by which clay minerals interact with semiconductor materials remains unknown. To this end, the present study was conducted to explore the formation of Brønsted acidic sites on the surface of mullite by modulating the cation types in mullite. It was hereby demonstrated for the first time that the presence of Brønsted acidic sites on the surface of clay minerals is conducive to the formation of N vacancies and dopant O in carbon nitride composites (CNM-30). The synergistic effect of N vacancy and doped O increases the specific surface area of CNM-30, enhances the electron-hole separation and transport efficiency, and ultimately makes CNM-30 produce more reactive oxygen species. CNM-30 possesses excellent degradation ability for gaseous phase pollutants (such as NO) and high concentration liquid phase pollutants (such as RhB and TC). Overall, this paper presents a new perspective on the design and development of semiconductor materials based on clay minerals.
科研通智能强力驱动
Strongly Powered by AbleSci AI