材料科学
氧化还原
镍
配体(生物化学)
磁性
电子顺磁共振
重量分析
金属
反铁磁性
无机化学
化学
核磁共振
有机化学
冶金
受体
物理
量子力学
生物化学
凝聚态物理
作者
Zixin Chang,Mengsu Zhu,Yong Sun,Feng He,Yang Li,Chunhui Ye,Yigang Jin,Ze Li,Wei Xu
标识
DOI:10.1002/adfm.202301513
摘要
Abstract Herein, a novel D 4 symmetrical redox‐active ligand tetrathia[8]circulene‐2,3,5,6,8,9,11,12‐octaol (8OH‐TTC) is designed and synthesized, which coordinates with Ni 2+ ions to construct a 2D conductive metal‐organic framework (2D c‐MOF) named Ni‐TTC. Ni‐TTC exhibits typical semiconducting properties with electrical conductivity up to ≈1.0 S m −1 at 298 K. Furthermore, magnetism measurements show the paramagnetic property of Ni‐TTC with strong antiferromagnetic coupling due to the presence of semiquinone ligand radicals and Ni 2+ sites. In virtue of its decent electrical conductivity and good redox activity, the gravimetric capacitance of Ni‐TTC is up to 249 F g −1 at a discharge rate of 0.2 A g −1 , which demonstrates the potential of tetrathia[8]circulene‐based redox‐active 2D c‐MOFs in energy storage applications.
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