Mechanism and growth kinetics of hexagonal TiO2 nanotubes with an influence of anodizing parameters on morphology and physical properties

Hexagonal TiO2 nanotubes (hTNTs) mimic a honeycomb structure, indicating their high potential as implantable materials due to their superior mechanical, chemical, and biological properties. However, the fabrication of hTNTs with a hexagonal base and six rectangular sides poses significant challenges, underscoring the importance of this research. This study developed a novel sonoelectrochemical method for synthesizing uniform hTNTs and evaluated the influence of anodizing parameters on their morphology. The effects of electrolyte concentration (ethylene glycol 90–97.5% and ammonium fluoride 0.1–0.5 wt%) and anodizing parameters (time 5–90 min, potential 10–80 V) on the morphology (diameter and length) and physical properties (porosity, specific surface area, growth factor) of hTNTs were investigated using scanning electron microscopy and anodization analysis. The methodology enabled the synthesis of hTNTs with diameters ranging from 33 ± 3 nm to 203 ± 33 nm and lengths from 1.16 ± 0.04 μm to 20.93 ± 2.37 μm. The study demonstrated that the concentrations of ethylene glycol and ammonium fluoride influenced the diameter and length of hTNTs depending on the anodizing potential. Moreover, the anodizing potential significantly affected the diameter, while both potential and time impacted the length of hTNTs. The proposed method can modify material surfaces for diverse applications.