Multiple‐Resonance Extension and Spin‐Vibronic‐Coupling‐Based Narrowband Blue Organic Fluorescence Emitters with Over 30% Quantum Efficiency

) coupled with large spin-vibronic coupling mediated by low-lying triplet excited states. An OLED fabricated using the MR-TADF emitter with CIE color coordinates of (0.12, 0.16) exhibits a record high EQE of 30.9% and a small FWHM of 23 nm. With further optimization of the device structure, a high EQE of 33.8% is achieved without additional outcoupling enhancements owing to the near-perfect horizontal alignment of the emitting dipoles.